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UKF Stainless Ltd
12 Buntsford Park Road
Bromsgrove
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B60 3DX

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1.4462

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Introduction:

A widely used duplex steel with a PREN about 34. Duplex steels combine high strength and corrosion resistance. With a near equal mix of austenite and ferrite, they give yield strengths 30% higher and tensile strengths marginally higher than comparable nitrogen-containing austenitics. Their resistance to stress-corrosion cracking in neutral chlorides is superior to that of the 18/10 and 18/12/3 austenites. In high chloride acidic or moderately sour environments where hydrogen or sulphide stress cracking is more likely, higher alloyed austenitcs need also to be considered.
Impact values are high and transition temperatures of base materials vary around -50°C. However, the proportion and orientation of ferrite in welds and base materials may significantly affect toughness at subzero temperatures.
Exposure to moderate and high temperatures and less rapid cooling may cause embrittlement. Accordingly, design stress values in ASME II and BS 5500-1991 do not extend above 300-315°C for S31803/S39205/X2 CrNiMoN 22 5 3.
Metallurgy:

When ferrite forming elements (Cr,Mo,Si,Nb) are kept at high levels but austenite promoting elements (Ni,Mn,N,C) are reduced, stainless steels with a mixed or duplex microstructure are produced. Mixtures of 40-60% of either phase are near optimum. Careful control of both composition and cooling rate from high temperatures is necessary to prevent the steel or weldment containing large amounts of ferrite
and/or traces of sigma phase that both embrittle and impair corrosion resistance. Welding requires control of heat-input and thermal cycles plus use of special consumables enriched with nitrogen and/or nickel. Duplex stainless steels may suffer severe embrittlement due to sigma phase formation in the 550-900°C range and from alpha prime in the 280-550°C range. The period for embrittlement may be short or long depending on composition, time, temperature and amount of cold work.
Composition:

 Element
Minimum (%)
Maximum (%)
 Chromium
21.00
23.00
 Nickel
4.50
6.50
 Molybdenum
2.50
3.50
 Nitrogen
0.08
0.20
 Manganese
-
2.00
 Carbon
-
0.03
Similiar Specifications:

  • ASTM UNS S31803

         21-23%Cr, 4.5-6.5%Ni, 2.5-3.5%Mo, 0.08-0.20%N, <2%Mn, <0.03%C
  • BS 318S13

         21-23%Cr, 4.5-6.5%Ni, 2.5-3.5%Mo, 0.08-0.20%N, <2%Mn, <0.03%C
  • DIN/SEW X2 CrNiMoN 22 5 3 1.4462

         21-23%Cr, 4.5-6.5%Ni, 2.5-3.5%Mo, 0.08-0.20%N, <2%Mn, <0.03%C
    Applications:

  • Offshore piping and tubing.
          Chemical tankers.
          Chemical and petrochemical industries.
          Flue gas desulphurization - scrubbers and chimneys.
          Plup and paper - press rolls and filter washers.
    Product Forms:

  • Plate,sheet & strip

          ASTM UNS S31803 240, 480
          BS 318S13 1501/3
  • Bar & long products

          ASTM UNS S31803 276
  • Forgings & others

          ASTM UNS S31803 182, 815
  • Tube

          ASTM UNS S31803 789
  • Pipe

          ASTM UNS S31803 790
  • General

          BS 318S13 5500
          DIN/SEW X2 CrNiMoN 22 5 3 1.4462 SEW400
     
    Page Last Modified: 7/04/06 17:21


     
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