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View Details
S32304 / S39230

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Introduction:

This steel has the attributes of other duplex steels - ie. high strength and good chloride stress corrosion cracking resistance, but due to its economic lean alloy content has a lower level of pitting and crevice-corrosion resistance (PREN about 26). Tests rank it between 18Cr10Ni and 17Cr13Ni3Mo.
Exposure to moderate and higher temperatures and less rapid cooling may cause embrittlement. Accordingly, design stress values in ASME II do not extend above 315°C for S32304 / S39230 / X2 CrNiN 23 4.
Impact values are high at room temperature with transition temperatures of base material around -100°C. However, the proportion and orientation of ferrite in welds and base material may affect toughness at subzero temperatures.
Metallurgy:

When ferrite forming elements (Cr,Mo,Si,Nb) are kept at high levels but austenite promoting elements (Ni,Mn,N,C) are reduced, stainless steels with a mixed or duplex microstructure are produced. Mixtures of 40-60% of either phase are near optimum.
Careful control of both composition and cooling rate from high temperatures is necessary to prevent the steel or weldment containing large amounts of ferrite and/or traces of sigma phase that both embrittle and impair corrosion resistance. Welding requires control of heat-input and thermal cycles plus use of special consumables enriched with nitrogen and/or nickel.
Duplex stainless steels may suffer severe embrittlement due to sigma phase formation in the 550-900°C range and from alpha prime in the 280-550°C range. The period for embrittlement may be short or long depending on composition, time, temperature and amount of cold work.
Composition:

 Element
Minimum (%)
Maximum (%)
 Chromium
21.50
24.50
 Nickel
3.00
5.50
 Molybdenum
0.05
0.06
 Nitrogen
0.05
0.20
 Manganese
-
2.50
 Carbon
-
0.03
 Copper
0.05
0.60
Similiar Specifications:

  • ASTM UNS S32304

         21.5-24.5%Cr, 3-5.5%Ni, 0.05-0.60%Mo, 0.05-0.20%N, <2.5%Mn, <0.03%C, 0.05-0.60%Cu
  • DIN/SEW X2 CrNiN 23 4 1.4362

         21.5-24.5%Cr, 3.0-5.5%Ni, <0.6%Mo, 0.05-0.20%N, <2.5%Mn, <0.03%C
    Applications:
  • Structural - replacement for carbon steel in corrosive service - eg. mine pit props, tubing, piping,
          tensioning systems.
          Pressure tubing and reactors.
          Module cladding
    Product Forms:

  • Plate,sheet & strip

          ASTM UNS S32304 240, 480
  • Tube

          ASTM UNS S32304 789
  • Pipe

          ASTM UNS S32304 790
  • General

          DIN/SEW X2 CrNiN 23 4 1.4362 SEW400
     
    Page Last Modified: 7/04/06 17:56


     
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